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(2S,4S)-1-tBoc-4-diphenylphosphino-2-(diphenylphosphinomethyl)pyrrolidine

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Formula: C34H37NO2P2
CAS: 61478-28-2

Identification

Structural Formula
(2S,4S)-1-tBoc-4-diphenylphosphino-2-(diphenylphosphinomethyl)pyrrolidine
CAS:
61478-28-2
EINECS:
Molecular Formula:
C34H37NO2P2
MDL:
MFCD01631275
SMILES:
CC(C)(C)OC(=O)N1C[C@H](C[C@H]1CP(C1=CC=CC=C1)C1=CC=CC=C1)P(C1=CC=CC=C1)C1=CC=CC=C1
Synonym:
(2s,4s)-(-)-1-tboc-4-diphenylphosphino-2-(diphenylphosphinomethyl)pyrrolidine ; (2s,4s)-(-)-n-boc-4-diphenylphosphino-2-diphenylphosphinomethyl-pyrrolidine ; boc-diphenylphosphino-diphenylphosphino- methyl-pyrrolidine ; (2s,4s)-1-boc-4-diphenylphosphino-2-(diphenylphosphinomethyl)pyrrolidine ; bppm, (2s,4s)-1-boc-4-diphenylphosphino-2-(diphenylphosphinomethyl)pyrrolidine ; (2s,4s)-n-butoxycarbonyl-4-diphenylphosphino-2-(diphenylphosphinomethyl)pyrrolid ; (2s,4s)-bppm ; (-)-bppm ; bppm ; (2s,4s)-(-)-1-boc-4-diphenylphosphino-2-(diphenylphosphinomethyl)pyrrolidine


Description

Chiral phosphine ligand for the rhodium catalyzed asymmetric hydrogenation of ketones and olefins. α-Amino acids are obtained in very high optical purity Hydrogenation of ketones to alcohols Hydroformylation.


Suppliers

Santa Cruz Biotechnology, Inc.
256383
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Hangzhou MolCore BioPharmatech Co.,Ltd.
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Leap Chem Co., Ltd
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Hangzhou J&H Chemical Co., Ltd.
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Finipharma Ltd
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(2S,4S)-1-tert-Butoxycarbonyl-4-diphenylphosphino-2-(diphenylphosphinomethyl)pyrrolidine
Argus Chemicals srl
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tert-butyl (2S,4S)-4-diphenylphosphanyl-2-(diphenylphosphanylmethyl)pyrrolidine-1-carboxylate
Manchester Organics Limited
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Prices & Availability




Data is processed


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Properties for (2S,4S)-1-tBoc-4-diphenylphosphino-2-(diphenylphosphinomethyl)pyrrolidine

Molecular Weight:
553.61 g·mol−1
Melting point:
96-100 °C
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Hazard Statements

GHS07

GHS03
Harmful
  • Acute toxicity (oral, dermal, inhalation), category 4
  • Skin irritation, categories 2, 3
  • Eye irritation, category 2A
  • Skin sensitization, category 1
  • Specific target organ toxicity following single exposure, category 3
    - Respiratory tract irritation
    - Narcotic effects
  • Not used
  • with the "skull and crossbones" pictogram
  • for skin or eye irritation if:
  • the "corrosion" pictogram also appears
  • the "health hazard" pictogram is used to indicate respiratory sensitization

Safety & Transport Information

Risk Codes:
R36/37/38 - Irritating to eyes, respiratory system and skin
Safety Codes:
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36 - Wear suitable protective clothing
Hazard Symbols:
Xi
Hazard symbol Xi
Storage temperature :
2-8°C
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Alternative Distributors of [(2S,4S)-1-tBoc-4-diphenylphosphino-2-(diphenylphosphinomethyl)pyrrolidine]

Producers or manufacturers change the product range from time to time. The following companies
have appeared as suppliers in the past / currently not verified

Conlon Limited | Chengdu Qiaofeng Technological Development Co., Ltd. | Shanghai AOKChem Group Limited | Sanowart Group Co., Ltd. | Anix-Chem Limited | Jinan Great Chemical Co., Ltd. | East Chemical Industry Co., Ltd. | Watson International Ltd | Jinan Haohua Industry Co., Ltd.

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MSDS:
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